COPPER MEDIATED CONVERSION OF ARENES AND ALKENES TO ESTERS, ALCOHOLS, AND ALDEHYDE PRODUCTS
卷宗概要
申请人
William L. Schinski; University of Virginia Patent Foundation
发明人
Thomas Brent Gunnoe; Junqi Chen; Fanji Kong; William L. Schinski
IPC 分类
CPC 分类
Described herein are methods for producing an aryl ester or vinyl ester, the method comprising reacting an aromatic compound or an alkene with CuX, wherein X is a carboxylate group having the formula RC(O)O—, wherein R is an alkyl group. The methods described herein provide an efficient method for esterifying aromatic compounds and alkenes to produce aryl and vinyl ester that subsequently can be converted to other useful industrial compounds including, but not limited to, alcohols. Also described herein are methods for recycling CuXfor further reactions thus rendering CuXas a net catalyst.
原文(中文)
Described herein are methods for producing an aryl ester or vinyl ester, the method comprising reacting an aromatic compound or an alkene with CuX, wherein X is a carboxylate group having the formula RC(O)O—, wherein R is an alkyl group. The methods described herein provide an efficient method for esterifying aromatic compounds and alkenes to produce aryl and vinyl ester that subsequently can be converted to other useful industrial compounds including, but not limited to, alcohols. Also described herein are methods for recycling CuXfor further reactions thus rendering CuXas a net catalyst.