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COPPER MEDIATED CONVERSION OF ARENES AND ALKENES TO ESTERS, ALCOHOLS, AND ALDEHYDE PRODUCTS

发明专利审中
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17权利要求 · 1 独立
§ Ⅰ

卷宗概要

发明人

Thomas Brent Gunnoe; Junqi Chen; Fanji Kong; William L. Schinski

IPC 分类

C7C 67/4B1J 31/22B1J 38/40

CPC 分类

C7C67/4B1J31/2239B1J38/40C7C2531/22

Described herein are methods for producing an aryl ester or vinyl ester, the method comprising reacting an aromatic compound or an alkene with CuX, wherein X is a carboxylate group having the formula RC(O)O—, wherein R is an alkyl group. The methods described herein provide an efficient method for esterifying aromatic compounds and alkenes to produce aryl and vinyl ester that subsequently can be converted to other useful industrial compounds including, but not limited to, alcohols. Also described herein are methods for recycling CuXfor further reactions thus rendering CuXas a net catalyst.

原文(中文)

Described herein are methods for producing an aryl ester or vinyl ester, the method comprising reacting an aromatic compound or an alkene with CuX, wherein X is a carboxylate group having the formula RC(O)O—, wherein R is an alkyl group. The methods described herein provide an efficient method for esterifying aromatic compounds and alkenes to produce aryl and vinyl ester that subsequently can be converted to other useful industrial compounds including, but not limited to, alcohols. Also described herein are methods for recycling CuXfor further reactions thus rendering CuXas a net catalyst.