SODIUM METAL BATTERY AND ELECTROCHEMICAL APPARATUS

原文（中文）

A sodium metal battery and an electrochemical apparatus, the battery has a positive electrode sheet and a negative electrode sheet, the negative electrode sheet being a negative electrode current collector, and a sodium layer deposited in situ on the negative electrode current collector having a thickness of ≥30 nm after the battery is charged and discharged for the first time. After the battery cell is charged and discharged for the first time, the amount of residual sodium metal is sufficient to uniformly form a sodium deposition layer with a certain thickness on the surface of the negative electrode current collector. The higher nucleation energy required for the deposition of sodium onto the surface of the current collector during subsequent charge-discharge cycles is avoided, the overall deposition overpotential is reduced, and the deposition uniformity of sodium metal and the reversibility of the charge-discharge process are ensured.