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LIGHT ALKANE CHROMIUM-BASED DEHYDROGENATION CATALYST, AND PREPARATION METHOD AND APPLICATION THEREOF

InventionPending
10Claims · 1 independent
§ Ⅰ

Dossier Overview

Inventor

Chunxue ZHANG; Runsheng ZHUO; Qiushi SUN; Bing LIU; Yusen RAO; Xingyue LAN; Ruiling ZHAO; Xinsheng LIU

IPC Classification

B1J 23/26B1J 35/40B1J 35/61B1J 35/70B1J 37/2B1J 37/12C7C 5/333

CPC Classification

B1J23/26B1J35/40B1J35/613B1J35/615B1J35/70B1J37/213B1J37/12C7C5/3332C7C2523/26

The present invention discloses a light alkane chromium-based dehydrogenation catalyst, and a preparation method and application thereof, and belongs to the field of petrochemical technology. The dehydrogenation catalyst has a spinel structure and comprises the following components in mass fractions based on the total weight on a dry basis: 0.1-35% of chromium oxide, 0.1-5% of a first promoter, 0.1-10% of a second promoter, 0.1-5% of a third promoter, and the balance being a fluidized bed carrier. This dehydrogenation catalyst controls the existence state of the active centers in the catalyst by adjusting the electrical properties of the surface of the carrier, resulting in higher dehydrogenation activity and propylene selectivity of the catalyst; at the same time, it enhances the overall stability, strength, and attrition of the catalyst, alleviating the loss problem of the catalyst during use.

Original (Chinese)

The present invention discloses a light alkane chromium-based dehydrogenation catalyst, and a preparation method and application thereof, and belongs to the field of petrochemical technology. The dehydrogenation catalyst has a spinel structure and comprises the following components in mass fractions based on the total weight on a dry basis: 0.1-35% of chromium oxide, 0.1-5% of a first promoter, 0.1-10% of a second promoter, 0.1-5% of a third promoter, and the balance being a fluidized bed carrier. This dehydrogenation catalyst controls the existence state of the active centers in the catalyst by adjusting the electrical properties of the surface of the carrier, resulting in higher dehydrogenation activity and propylene selectivity of the catalyst; at the same time, it enhances the overall stability, strength, and attrition of the catalyst, alleviating the loss problem of the catalyst during use.

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